Monday 20 January 2014

BOHR'S ATOMIC THEORY

                                          
In atomic physics, the Bohr model, introduced by Niels Bohr in 1913, depicts the atom as a small, positively charged nucleus surrounded by electrons that travel in circular orbits around the nucleus—similar in structure to the solar system, but with attraction provided by electrostatic forces rather than gravity. After the cubic model (1902), the plum-pudding model (1904), the Saturnian model (1904), and the Rutherford model (1911) came the Rutherford–Bohr model or just Bohr model for short (1913). The improvement to the Rutherford model is mostly a quantum physical interpretation of it. The Bohr model has been superseded, but the quantum theory remains sound.
The model's key success lay in explaining the Rydberg formula for the spectral emission lines of atomic hydrogen. While the Rydberg formula had been known experimentally, it did not gain a theoretical underpinning until the Bohr model was introduced. Not only did the Bohr model explain the reason for the structure of the Rydberg formula, it also provided a justification for its empirical results in terms of fundamental physical constants.
The Bohr model is a relatively primitive model of the hydrogen atom, compared to the valence shell atom. As a theory, it can be derived as a first-order approximation of the hydrogen atom using the broader and much more accurate quantum mechanics, and thus may be considered to be an obsolete scientific theory. However, because of its simplicity, and its correct results for selected systems (see below for application), the Bohr model is still commonly taught to introduce students to quantum mechanics, before moving on to the more accurate, but more complex, valence shell atom. A related model was originally proposed by Arthur Erich Haas in 1910, but was rejected. The quantum theory of the period between Planck's discovery of the quantum (1900) and the advent of a full-blown quantum mechanics (1925) is often referred to as the old quantum theory.

ORIGIN
 

In the early 20th century, experiments by Ernest Rutherford established that atoms consisted of a diffuse cloud of negatively charged electrons surrounding a small, dense, positively charged nucleus. Given this experimental data, Rutherford naturally considered a planetary-model atom, the Rutherford model of 1911 – electrons orbiting a solar nucleus – however, said planetary-model atom has a technical difficulty. The laws of classical mechanics (i.e. the Larmor formula), predict that the electron will release electromagnetic radiation while orbiting a nucleus. Because the electron would lose energy, it would gradually spiral inwards, collapsing into the nucleus. This atom model is disastrous, because it predicts that all atoms are unstable.
Also, as the electron spirals inward, the emission would gradually increase in frequency as the orbit got smaller and faster. This would produce a continuous smear, in frequency, of electromagnetic radiation. However, late 19th century experiments with electric discharges have shown that atoms will only emit light (that is, electromagnetic radiation) at certain discrete frequencies.
To overcome this difficulty, Niels Bohr proposed, in 1913, what is now called the Bohr model of the atom. He suggested that electrons could only have certain classical motions:

  1.  Electrons in atoms orbit the nucleus.
  2.  The electrons can only orbit stably, without radiating, in certain orbits (called by Bohr the "stationary orbits"): at a certain discrete set of distances from the nucleus. These orbits are associated with definite energies and are also called energy shells or energy levels. In these orbits, the electron's acceleration does not result in radiation and energy loss as required by classical electromagnetics.
  3.  Electrons can only gain and lose energy by jumping from one allowed orbit to another, absorbing or emitting electromagnetic radiation with a frequency ν determined by the energy difference of the levels according to the Planck relation
\Delta{E} = E_2-E_1=h\nu \ ,
where h is Planck's constant. The frequency of the radiation emitted at an orbit of period T is as it would be in classical mechanics; it is the reciprocal of the classical orbit period:  
 \nu = {1\over T}.

The significance of the Bohr model is that the laws of classical mechanics apply to the motion of the electron about the nucleus only when restricted by a quantum rule. Although rule 3 is not completely well defined for small orbits, because the emission process involves two orbits with two different periods, Bohr could determine the energy spacing between levels using rule 3 and come to an exactly correct quantum rule: the angular momentum L is restricted to be an integer multiple of a fixed unit:
 L = n{h \over 2\pi} = n\hbar
 where n = 1, 2, 3, ... is called the principal quantum number, and ħ = h/2π. The lowest value of n is 1; this gives a smallest possible orbital radius of 0.0529 nm known as the Bohr radius. Once an electron is in this lowest orbit, it can get no closer to the proton. Starting from the angular momentum quantum rule, Bohr was able to calculate the energies of the allowed orbits of the hydrogen atom and other hydrogen-like atoms and ions.

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